Design and synthesis of bistereogenic chiral ionic liquids and their use as solvents for asymmetric Baylis-Hillman reactions

Satish Garre; Erica Parker; Bukuo Ni; Allan D. Headley

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Design and synthesis of bistereogenic chiral ionic liquids and their use as solvents for asymmetric Baylis-Hillman reactions

机译：双水生手性离子液体的设计和合成及其作为不对称Baylis-Hillman反应的溶剂的用途

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Three novel chiral ionic liquids (CILs) containing two chiral centers in the side chain bonded to the 2-position of the imidazolium cation and different anions have been synthesized, characterized and used as chiral solvents for asymmetric Baylis-Hillman (BH) reactions; good yields and fair enantioselectivities were obtained.

机译：合成了三种新型的手性离子液体（CIL），在侧链上有两个手性中心键合到咪唑鎓阳离子的2位和不同的阴离子上，表征并用作不对称Baylis-Hillman（BH）反应的手性溶剂；获得了良好的产率和公平的对映选择性。

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《Organic & biomolecular chemistry》 |2008年第17期|3041-3043|共3页
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Satish Garre; Erica Parker; Bukuo Ni; Allan D. Headley;
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1. Chiral ionic liquids, a renewal for the chemistry of chiral solvents? Design, synthesis and applications for chiral recognition and asymmetric synthesis [J] . Baudequin C, Bregeon D, Levillain J, Tetrahedron, Asymmetry: The International Journal for Repid Publication on all Aspects of Asymmetry in Orgainc, Inorganic, Organometallic, Physical and Bio-Organic Chemistry . 2005,第24期

机译：手性离子液体，手性溶剂化学的更新？手性识别和不对称合成的设计，合成及应用
2. First application of chiral ionic liquids in asymmetric Baylis-Hillman reaction [J] . Bruce Pegot, Giang Vo-Thanh, Didier Gori, Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2004,第34期

机译：手性离子液体在不对称Baylis-Hillman反应中的首次应用
3. First application of chiral ionic liquids in asymmetric Baylis-Hillman reaction [J] . Bruce Pegot, Giang Vo-Thanh, Didier Gori, Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2004,第34期

机译：手性离子液体在不对称Baylis-Hillman反应中的首次应用
4. Asymmetric Reactions using Novel Chiral Ionic Liquids [C] . Luis C. Branco, Rui Costa, Andreia Rosatella European Symposium on Organic Chemistry . 2009

机译：使用新型手性离子液体的不对称反应
5. Design and synthesis of novel chiral arsines for asymmetric Wittig reactions and palladium-catalyzed asymmetric allylic alkylation and asymmetric Heck reactions. [D] . Wu, Huafeng. 2004

机译：设计和合成用于不对称Wittig反应和钯催化的不对称烯丙基烷基化和不对称Heck反应的新型手性ral。
6. Coordinating Chiral Ionic Liquids: Design Synthesis and Application in Asymmetric Transfer Hydrogenation under Aqueous Conditions [O] . Maria Vasiloiu, Peter Gaertner, Ronald Zirbs, -1

机译：配位手性离子液体的设计合成及其在水性条件下不对称转移加氢中的应用
7. Novel chiral phosphonium ionic liquids as solvents and catalysts for cycloadditions. Investigation of the Diels-Alder reaction of a series of dienes and dienophiles in novel chiral phosphonium ionic liquids. [O] . Yu Jianguo 2009

机译：新型手性phospho离子液体作为环加成的溶剂和催化剂。在新型手性phospho离子液体中一系列二烯和亲二烯体的Diels-Alder反应的研究。

Design and synthesis of bistereogenic chiral ionic liquids and their use as solvents for asymmetric Baylis-Hillman reactions

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