Enantioselective construction of lactone[2,3-b]piperidine skeletons via organocatalytic tandem reactions

Zhao-Quan He; Bo Han; Rui Li; Li Wu; Ying-Chun Chen

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Enantioselective construction of lactone[2,3-b]piperidine skeletons via organocatalytic tandem reactions

机译：通过有机催化串联反应对内酯[2,3-b]哌啶骨架的对映选择性构建

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摘要

A highly enantioselective construction of δ- and γ-lactone[2,3-b]piperidine skeletons was accomplished by tandem aza-Diels-Alder reaction-hemiacetal formation-oxidation from N-Tos-1-aza-1,3-butadienes and aliphatic dialdehydes.

机译：通过N-Tos-1-aza-1,3-丁二烯和N-Tos-1-aza-1,3-丁二烯的串联aza-Diels-Alder反应-半缩醛形成-氧化完成δ-和γ-内酯[2,3-b]哌啶骨架的高度对映选择性。脂族二醛。

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《Organic & biomolecular chemistry 》 |2010年第4期| 755-757| 共3页
作者
Zhao-Quan He; Bo Han; Rui Li; Li Wu; Ying-Chun Chen;
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State Key Laboratory of Biotherapy, West China Hospital, Sichuan University, Chengdu, 610041, China Key Laboratory of Drug-Targeting and Drug Delivery System of Education Ministry, Department of Medicinal Chemistry, West China School of Pharmacy, Sichuan University, Chengdu, 610041, China;

Key Laboratory of Drug-Targeting and Drug Delivery System of Education Ministry, Department of Medicinal Chemistry, West China School of Pharmacy, Sichuan University, Chengdu, 610041, China;

State Key Laboratory of Biotherapy, West China Hospital, Sichuan University, Chengdu, 610041, China;

Key Laboratory of Drug-Targeting and Drug Delivery System of Education Ministry, Department of Medicinal Chemistry, West China School of Pharmacy, Sichuan University, Chengdu, 610041, China;

State Key Laboratory of Biotherapy, West China Hospital, Sichuan University, Chengdu, 610041, China Key Laboratory of Drug-Targeting and Drug Delivery System of Education Ministry, Department of Medicinal Chemistry, West China School of Pharmacy, Sichuan University, Chengdu, 610041, China;

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Enantioselective construction of lactone[2,3-b]piperidine skeletons via organocatalytic tandem reactions

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