Characterization of the irradiation-induced phase transition in the monoclinic polymorph of zirconia

摘要

Two groups of pure zirconia (ZrO_2) specimens with the monoclinic polymorph and distinct nanopowder size ranges of approximately 20-30 nm and 30-60 nm were irradiated separately at room temperature with 100 keV H~+ and 3 MeV Fe~(2+) ions to various fluences. Following TEM observations and XRD analyses, the irradiation with 100 keV protons to a fluence of over 3 × 10~(15) ions/cm~2 was demonstrated to induce transformation from monoclinic (m) to tetragonal (t) phases in the specimen with the size range of approximately 20-30 nm due to the energy crossover that facilitates the m → t transformation. However, the transformation did not occur in the irradiated specimen with the other size range even though the fluence of protons was up to 1 × 10~(17) ions/cm~2. Furthermore, although irradiation with 3 MeV Fe~(2+) ions brought about low electronic energy loss, the m → t transformation can be induced under the low fluence of 1 × 10~(14) ions/cm~2 because a high level of damage defects (oxygen vacancies) may promote the m → t transformation. Consequently, the largest crystallite size of t-ZrO_2 induced by the proton irradiation is approximately 29 nm, as a result of the metastable critical size effect of t-phase zirconia at room temperature.