An efficient synthesis of 2-cyano-2-phenyl-2,11b-dihydro-[1,3]oxazino[2,3-a]isoquinolines by reaction of isoquinoline with electron-deficient acetylenes in the presence of benzoylcyanide

Issa Yavari; Nargess Hosseini; Loghman Moradi

首页> 外文期刊>Monatshefte für Chemie / Chemical Monthly >An efficient synthesis of 2-cyano-2-phenyl-2,11b-dihydro-[1,3]oxazino[2,3-a]isoquinolines by reaction of isoquinoline with electron-deficient acetylenes in the presence of benzoylcyanide

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An efficient synthesis of 2-cyano-2-phenyl-2,11b-dihydro-[1,3]oxazino[2,3-a]isoquinolines by reaction of isoquinoline with electron-deficient acetylenes in the presence of benzoylcyanide

机译：在苯甲酰氰化物存在下，异喹啉与缺电子的乙炔反应，可有效合成2-氰基-2-苯基-2,11b-二氢-[1,3]恶嗪基[2,3-a]异喹啉

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Isoquinoline reacts with electron-deficient acetylenic compounds in the presence of benzoylcyanide to form 2-cyano-2-phenyl-2,11b-dihydro-[1,3]oxazino[2,3-a]isoquinolines in good yields.

机译：异喹啉在苯甲酰基氰化物的存在下与缺电子的炔属化合物反应，以高收率形成2-氰基-2-苯基-2,11b-二氢-[1,3]恶嗪基[2,3-a]异喹啉。

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《Monatshefte für Chemie / Chemical Monthly》 |2008年第8期|p.953-956|共4页
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Issa Yavari; Nargess Hosseini; Loghman Moradi;
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1,3; Oxazine; Electron; deficient acetylenes; Isoquinoline; Benzoylcyanide; N; Heterocycles.;

机译：1,3;恶嗪;电子;乙炔不足;异喹啉;苯甲酰氰;N;摩托车。;

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1. An efficient synthesis of 2-cyano-2-phenyl-2,11b-dihydro-[1,3]oxazino[2,3-a]isoquinolines by reaction of isoquinoline with electron-deficient acetylenes in the presence of benzoylcyanide [J] . Issa Yavari, Nargess Hosseini, Loghman Moradi Monatshefte fur Chemie . 2008,第8期

机译：在苯甲酰氰化物存在下，异喹啉与缺电子乙炔反应，可有效合成2-氰基-2-苯基-2,11b-二氢-[1,3]恶嗪基[2,3-a]异喹啉
2. The reaction of isoquinoline and dimethyl acetylenedicarboxylate with 1,2-and 1,4-benzoquinones: a novel synthesis of spiro[1,3]oxazino[2,3-a]isoquinolines [J] . Vijay Nair, A. R. Sreekanth, A. T. Biju, Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2003,第4期

机译：异喹啉和乙酰二羧酸二甲酯与1,2-和1,4-苯醌的反应：螺[1,3]恶嗪[2,3-a]异喹啉的新型合成
3. An efficient synthesis of 2-(trifluoromethyl)-2H-[1,3]oxazino[2,3-a] isoquinolines via a three-component cascade approach using a continuous-flow microreactor [J] . LeiM., TianW., HuR., Synthesis: International Journal of Methods in Synthetic Organic Chemistry . 2012,第16期

机译：使用连续流微反应器通过三组分级联方法有效合成2-（三氟甲基）-2H- [1,3]恶嗪[2,3-a]异喹啉
4. A facile synthesis of diastereoisomeric sulfur containing stable 1,4-diionic organophosphorus compounds through the reaction of 1,3-diethyl-2- thiobarbituric acid and activated acetylenic esters in the presence of triphenylphosphine(Abstracts) [C] . Nourollah Hazeri, Malek Taher Maghsoodlou, Sayyed Mostafa Habibi Khorassani European Symposium on Organic Chemistry . 2007

机译：通过1,3-二乙基-2-硫脲脲酸和在三苯基膦（摘要）存在下，通过1,3-二乙基-2-硫脲脲酸和活化的乙炔酯的反应，含有稳定的1,4-二硫酸有机磷化合物的非对映异构体硫的合成。
5. Diversity-Oriented Synthesis Based on the DPPP-Catalyzed Mixed Double-Michael Reactions of Electron-Deficient Acetylenes and β-Amino Alcohols [O] . Yi Chiao Fan, Ohyun Kwon 2011

机译：基于DPPP催化的缺电子乙炔与β-氨基醇混合双Michael反应的面向多样性的合成
6. Simple and one-pot synthesis of new heterocyclic compounds in three-component reactions between isoquinoline or phenanthridine and acetylenic esters in the presence of N-heterocycles or 1,3-dicarbonyl compounds [O] . Malek Taher Maghsoodlou, Mahmoud Nassiri, Reza Heydari, 2010

机译：在N-杂环或1,3-二羰基化合物存在下，在异喹啉或菲啶与炔基酯之间的三组分反应中简单和一锅法合成新的杂环化合物

An efficient synthesis of 2-cyano-2-phenyl-2,11b-dihydro-[1,3]oxazino[2,3-a]isoquinolines by reaction of isoquinoline with electron-deficient acetylenes in the presence of benzoylcyanide

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