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The role of delayed water curing in improving the mechanical and microstructural properties of alkali activated fly ash based geopolymer paste blended with slag

机译:延迟水固化在改善掺有矿渣的碱活化粉煤灰基地质聚合物浆料的机械和微观结构性能中的作用

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Purpose - This paper aims to investigate the effect of delayed water curing on the mechanical and microstructural properties of fly ash-based geopolymer paste-blended with Ground Granulated Blast Furnace Slag (GGBS) with different rest periods. Design/methodology/approach - The blended geopolymer paste was composed of GGBS (15 per cent of the total weight) and the base material, Fly Ash (FA). The blended mix was activated by activator solution (Sodium hydroxide and Sodium silicate) containing 6 per cent Na_20 of total base material. The effect of delayed water curing has been studied by gradually increasing the aging period (Rest Period) from 2 hours to 24 hours in the formation of activated outcome along with Calcium Silicate Hydrate (CSH). To analyze the mechanical and microstructural properties of the resultant blended geopolymer paste, compressive strength test, FESEM and XRD have been carried out. Moreover, a long-term durability test subjected to sulphate exposure has been performed to evaluate the durability of the designed sustainable geopolymer paste. Findings - The present paper shows that the delayed water curing incorporates secondary heat input enhancing the partial polymer formation along with CSH. Slag-blended AAFA-based geopolymer paste is seen to exhibit quick setting property. Also, AAFA-based geopolymer paste samples subjected to longer rest period show early strength gain at a high rate under water curing as compared to those subjected to the shorter rest period. Originality/value-To the best of authors' knowledge, the effect of delayed water curing on the mechanical and microstructural properties of slag-blended AAFA-based geopolymer paste has not been studied before.
机译:目的-本文旨在研究水滞后固化对粉煤灰基高聚物糊料与粉状高炉矿渣(GGBS)掺合在不同休息时间的力学和微观结构性能的影响。设计/方法/方法-混合的地质聚合物浆料由GGBS(占总重量的15%)和基础材料粉煤灰(FA)组成。通过包含总基础材料的6%Na_20的活化剂溶液(氢氧化钠和硅酸钠)活化混合的混合物。通过将老化时间(Rest Period)从2小时逐渐增加到硅酸钙水合物(CSH)的活化结果形成中,研究了延迟水固化的效果。为了分析所得共混地质聚合物糊的机械和微观结构性能,进行了抗压强度测试,FESEM和XRD。此外,已经进行了经受硫酸盐暴露的长期耐久性测试,以评估设计的可持续地质聚合物浆料的耐久性。研究结果-本文表明,延迟水固化结合了二次热输入,从而增强了部分聚合物与CSH的形成。可以看到基于AFA的掺混矿渣的地质聚合物浆具有快速固化的特性。而且,与经受较短静置时间的那些相比,经受较长静置时间的基于AAFA的地质聚合物糊剂样品在水固化下以高速率显示出早期强度增加。原创性/价值-据作者所知,延迟水固化对矿渣掺混AFAA基地质聚合物浆料的机械和微观结构性能的影响尚未进行过研究。

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