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CVD oriented growth of carbon nanotubes using AlPO_4-5 and L type zeolites

机译:使用AlPO_4-5和L型沸石的CVD定向生长碳纳米管

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摘要

Control over single wall carbon nanotube structure, positioning and orientation is one of the main challenges for the development of carbon nanotube based electronics. A novel approach consists in placing carbon nanotubes catalyst inside the pores of a zeolite so that control over the nanotube diameter and its growth direction can be achieved. We present the relation between CVD process and carbon nanotube growth when placing the catalyst inside the pores of AlPO_4-5 and L type zeolites. By SEM and Raman characterization, we have determined the influence of vacuum pre-treatment and catalyst activation steps. This is the first step towards obtaining batch synthesis of oriented nanotubes at wafer scale.
机译:对单壁碳纳米管的结构,位置和方向的控制是基于碳纳米管的电子学发展的主要挑战之一。一种新颖的方法在于将碳纳米管催化剂放置在沸石的孔内,从而可以控制纳米管直径及其生长方向。我们提出了将催化剂置于AlPO_4-5和L型沸石孔内时CVD工艺与碳纳米管生长之间的关系。通过SEM和拉曼光谱表征,我们确定了真空预处理和催化剂活化步骤的影响。这是在晶片规模上获得定向纳米管批量合成的第一步。

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