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Evaluation of the Properties of Polyaspartic Polyurea Coated Concrete Subjected to the Co-action of Freeze-Thaw Cycles and NaCl Solution Immersion

机译:冻融循环和NaCl溶液共同作用下的聚天冬氨酸聚脲涂层混凝土的性能评估

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摘要

The deterioration of coated concrete subjected to co-action of freeze-thaw cycles-NaCl solution immersion double factors exposure was investigated in this study. Adhesion, chloride content and resistance of chloride ion diffusivity of two types of polyaspartic ester polyurea coated concrete were analyzed. Test results showed that the adhesion of QF-1 (PAE-b-H_(12)MDI prepolymer H66) and QF-2 (PAE-b-H_(12)MDI prepolymer H62) coated concrete reduced about 5% respectively which kept excellent under the double factors exposure after 200, 300 days and 25, 50 times of cycles. The degradation process of coated concrete simultaneously exposed to co-action exposure was significantly accelerated. In co-action exposure tests, the average chloride ion content of coated concrete increased about 33% and 87% after 25 and 50 times of cycles compared with single NaCl solution immersion exposure; the chloride ion diffusion coefficient of concrete substrate increased with the increase of exposure time and freeze-thaw cycles. Freeze-thaw cycles results showed a severe influence on chloride ion diffusion and permeation of surface protection coating of concrete. Research also showed that the chloride ion diffusion of coated concrete subjected to the co-action of freeze-thaw cycles-NaCl solution was coincided with the Fick's second law.
机译:本研究研究了冻融循环-NaCl溶液浸泡双因素暴露共同作用下的涂层混凝土的劣化。分析了两种类型的聚天冬氨酸酯聚脲涂层混凝土的附着力,氯含量和耐氯离子扩散性。试验结果表明,QF-1(PAE-b-H_(12)MDI预聚物H66)和QF-2(PAE-b-H_(12)MDI预聚物H62)的涂覆混凝土的附着力分别降低了约5%,保持了优异的性能。在200、300天和25、50次循环后的双因素暴露下。同时暴露于协同作用下的带涂层混凝土的降解过程显着加快。在协同作用暴露测试中,与单次NaCl溶液浸没暴露相比,经过25和50次循环后,涂层混凝土的平均氯离子含量分别增加了约33%和87%。混凝土基材中氯离子的扩散系数随暴露时间和冻融循环时间的增加而增加。冻融循环结果表明,氯离子对混凝土表面保护层中氯离子​​的扩散和渗透具有严重的影响。研究还表明,经过冻融循环-NaCl溶液共同作用的带涂层混凝土中氯离子的扩散与菲克第二定律相吻合。

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