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Enhanced Fluorescence Emission of Bonding Type Rare Earth Complexes Eu(MAA)_3Phen

机译:键合型稀土配合物Eu(MAA)_3Phen的增强荧光发射

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摘要

Rare earth fluorescent complexes monomer with activated double bonds was synthesized by using Eu as the central atom, Methacrylic acid and 1, 10-Phenanthroline monohydrate as ligand. The structure of resultant Eu(MAA)_3Phen was determined by infrared spectrum, ultraviolet spectrum and element analysis, and the fluorescence property of the complexes was tested by fluorescence spectra and fluorescence microscopy. Compared with conventional luminescent materials, this resultant complexes show greater fluorescence intensity. The analysis has revealed that with the increase of rare earth ion concentration from 4×10~(-5)mol-L~(-1) to 4×10~(-3)mol-L~(-1), the fluorescence quenching phenomenon appeared in the complexes solution.
机译:以Eu为中心原子,甲基丙烯酸和1,10-邻菲咯啉一水合物为配体,合成了具有活化双键的稀土荧光配合物单体。通过红外光谱,紫外光谱和元素分析确定所得Eu(MAA)_3Phen的结构,并通过荧光光谱和荧光显微镜检查配合物的荧光性质。与常规的发光材料相比,这种所得的配合物显示出更大的荧光强度。分析表明,随着稀土离子浓度从4×10〜(-5)mol-L〜(-1)增加到4×10〜(-3)mol-L〜(-1),荧光络合物溶液中出现猝灭现象。

著录项

  • 来源
    《Materials science forum》 |2017年第3期|1839-1843|共5页
  • 作者单位

    State Key Laboratory for Modification of Chemical Fibers and Polymer Materials,College of Materials Science and Engineering, Donghua University, Shanghai 201620 China;

    State Key Laboratory for Modification of Chemical Fibers and Polymer Materials,College of Materials Science and Engineering, Donghua University, Shanghai 201620 China;

    State Key Laboratory for Modification of Chemical Fibers and Polymer Materials,College of Materials Science and Engineering, Donghua University, Shanghai 201620 China;

    State Key Laboratory for Modification of Chemical Fibers and Polymer Materials,College of Materials Science and Engineering, Donghua University, Shanghai 201620 China;

    State Key Laboratory for Modification of Chemical Fibers and Polymer Materials,College of Materials Science and Engineering, Donghua University, Shanghai 201620 China;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    Rare earth element; Complexes; Fluorescence emission function;

    机译:稀土元素;配合物;荧光发射功能;

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