Effect of chitosan content on gel content of epoxized natural rubber grafted with chitosan in latex form

摘要

The epoxidized natural rubber (ENR) latex-g-chitosan (ENR-g-chitosan) was prepared in latex form using potassium persulphate as an initiator. Firstly, the reduction in molecular weight of chitosan was subjected to the addition of K_2S_2O_8 at 70 ℃ for 15 min. The structure of the modified chitosan was characterized by ATR-FTIR. Secondarily, the influence of chitosan contents, reaction time, and temperature and K_2S_2O_8 concentrations on the gel content of the modified ENR was investigated. The chemical structure of the ENR-g-chitosan was confirmed by ~1H-NMR and ATR-FTIR. The ether linkage of the ENR-g-chitosan was conformed at 1154 an 1089 cm~(-1) by ATR-FTIR and 3.60 ppm by ~1H-NMR. The gel content of ENR-g-chitosan at 5% chitosan showed the highest value compared with other samples. But when chitosan increased from 5% to 10% or 20%, the gel content of ENR-g-chitosan dramatically decreased. The ENR-g-chitosan showed good thermal resistance due to incorporation of chitosan. The morphology of ENR-g-chitosan particle showed the core-shell structure observed by TEM. The optimum condition of grafting ENR with chitosan was found at 65 ℃ For 3 h of reaction time, ratio of ENR/chitosan at 9∶1.