Localized corrosion behavior of 316L stainless steel in the presence of sulfate-reducing and iron-oxidizing bacteria

摘要

Localized corrosion behavior of 316L stainless steel was investigated in the presence of sulfate-reducing bacteria (SRB) and iron-oxidizing bacteria (IOB) isolated from cooling water system using polarization measurement, scanning electron microscopy (SEM) examinations and energy dispersive spectrum (EDS) analysis. The results show the corrosion potential (E_(corr)) and breakdown potential (E_b) of SS decreased in turn with the presence of IOB, SRB and SRB + IOB, indicating decreased relative resistance to localized corrosion. E_(corr) in the sterile medium remained virtually unchanged with exposure time, indicating that localized attack did not occur. However, micrometer-scale pitting was observed on the SS surface in the presence of bacteria. The presence of SRB demonstrated higher corrosion rates than IOB. The combination of SRB and IOB yielded the highest corrosion rate. The presence and metabolic activities of bacteria on SS surface produce environments that can alter rates of partial reactions in corrosion processes and shift corrosion mechanisms. The most severe microbiologically induced corrosion takes place in aquatic solution where physiological groups of aerobic and anaerobic microorganisms interact.