In situ preparation of composite from conjugated polyschiff bases and multiwalled carbon nanotube: Synthesis, electrochromic, acidochromic properties

摘要

Polyschiff base (PSB) which has the structure of C=N double bond is well known as conducting material with high thermal resistance, chemical and electrical properties. Recently, it was used as hole transporting material in organic light emitting diode (OLED), chemical sensor and electrochromic materials. Carbon nanotubes (CNTs) with excellent properties such as unique electrical, mechanical, optical and chemical properties are promising reinforcing materials for polymer composites which improve the comprehensive properties of polymers. In this paper, conjugated PSB-grafted multiwalled carbon nanotubes (MWNTs) composite was prepared by in situ polymerization. The resultant composites were characterized by thermogravimetric (TGA), scanning electron microscopy (SEM), UV-vis absorption, pho-toluminescence (PL), cyclic voltammograms (CV), infrared spectroscopy (1R) and Raman spectroscopy. The composites exhibited high thermal stability and excellent reversibilities of electrochromic, pho-tochromic, acidochromic characteristics, with the color change from the light yellow to blue.