Fabrication of pseudo-pi vertical alignment mode liquid crystal devices with ultra-violet polymerisation and investigations of their electro-optical characteristics

摘要

In this study, we applied the non-contact photo-polymerisation method in fabricating pseudo-polyimide (PI) liquid crystal (LC) devices with vertical alignment copolymer films, in the hope of solving the problems associated with traditional rubbing alignment processes. We mixed different photo-polymerisation-type acrylic monomers and negative dielectric anisotropy LC at proper weight percentages, and induced phase separation behaviour between the photo-polymerisation-type acrylic monomers and the LC molecules in the LC mixture solution through ultra-violet light irradiation, thereby forming copolymer films with vertical alignment effects. We further conducted preliminary characterisation of the alignment mechanism, photo-polymerisation, etc., of the LC molecules and investigated their interactions with alkyl acrylic monomers with different carbon chain lengths (the analogue of alkyl side chains in traditionally used vertical alignment-type PI) and electro-optical properties such as the transmittance, contrast ratio, and response time.