Fireproofing wood using borate and vinyl phosphorus compounds and its water resistant treatment using copolymer of dimethyl vinylphosphonate and methyl methacrylate

摘要

Vinyl phosphorus compounds such as poly (vinyl phosphonic acid) (PVPA), poly (dimethyl vinyl phosphonate) (PDMVP) impart high flame retardancy to wood comparable to conventional fireproofing wood by combined use of sodium polyborate (SPB) in contrast to their single use. The differential thermal analysis and thermogravimetry (DTA/TG) suggest a synergy effect between SPB and PVPA. The water resistance of the treated wood is improved by copolymerization of dimethyl vinyl phosphonate (DMVP) with methyl methacrylate (MMA) inside the wood after the impregnation of SPB, and the incombustibility of the wood is mostly maintained after leaching tests. The combustion residues of the wood treated with DMVP and MMA after SPB show high compressive strength, and their SEM images suggest that the strength is due to formed charcoal.