Isolation and Structural Characterization of the Terminal Mesityl Azide Complex V(N_3Mes)(Ⅰ)(NRAr_F)_2 and Its Conversion to a Vanadium(Ⅴ) Imido Complex

Michael G. Fickes; William M. Davis; Christopher C. Cummins

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Isolation and Structural Characterization of the Terminal Mesityl Azide Complex V(N_3Mes)(Ⅰ)(NRAr_F)_2 and Its Conversion to a Vanadium(Ⅴ) Imido Complex

机译：末端异氰酸叠氮配合物V（N_3Mes）（Ⅰ）（NRAr_F）_2的分离，结构表征及其向钒（Ⅴ）亚氨基配合物的转化

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We have established the structure of a rare organoazide complex of vanadium and have begun to delineate the conditions under which it extrudes dinitrogen to provide a structurally similar arylimido derivative. Future work will concentrate on the mechanism of N_2 extrusion from 1 and on other possible modes of reaction for this complex.

机译：我们已经建立了稀有的钒有机叠氮化物络合物的结构，并开始描述了其挤出二氮以提供结构相似的芳基酰亚胺衍生物的条件。未来的工作将集中在从1挤出N_2的机理以及该配合物的其他可能的反应方式上。

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《Journal of the American Chemical Society》 |1995年第23期|p.6384-6385|共2页
作者
Michael G. Fickes; William M. Davis; Christopher C. Cummins;
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Department of Chemistry Massachusetts Institute of Technology Cambridge, Massachusetts 02139;

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收录信息美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);美国《化学文摘》(CA);
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正文语种 eng
中图分类化学;
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入库时间 2022-08-18 03:26:24

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Isolation and Structural Characterization of the Terminal Mesityl Azide Complex V(N_3Mes)(Ⅰ)(NRAr_F)_2 and Its Conversion to a Vanadium(Ⅴ) Imido Complex

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