Regiochemical Control in the Metal-Catalyzed Transposition of Allylic Silyl Ethers

摘要

In the context of manipulating synthetic intermediates,the efficient [1,3]-transposition of allylic heteroatom functionalities is an important goal in synthetic chemistry.One of the most direct and atom-economical methods for this transformation is a transition-metal-catalyzed rearrangement of an allylic hydroxyl group.