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C_(72)Cl_4: A Pristine Fullerene with Favorable Pentagon-Adjacent Structure

机译:C_(72)Cl_4:具有良好五边形相邻结构的原始富勒烯

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摘要

A long-sought empty non-IPR fullerene, ~(#11188)C_(72), which is more stable than the sole I PR isomer in the fullerene[72] family, has been retrieved and crystallographically characterized as ~(#11188)C_(72)Cl4. Mass spectrometric data support the facile dechlo-rination of ~(#11188)C_(72)Cl_4 and, in turn, the possible stability of pristine ~(#11188)C_(72).
机译:已检索到一个长期寻求的空非IPR富勒烯〜(#11188)C_(72),比富勒烯[72]家族中唯一的I PR异构体更稳定,其晶体学特征为〜(#11188) C_(72)Cl4。质谱数据支持〜(#11188)C_(72)Cl_4的轻松脱氯,进而支持原始〜(#11188)C_(72)的可能的稳定性。

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  • 来源
    《Journal of the American Chemical Society》 |2010年第48期|p.17102-17104|共3页
  • 作者单位

    State Key Laboratory of Physical Chemistry of Solid Surfaces and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China;

    State Key Laboratory of Physical Chemistry of Solid Surfaces and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China;

    State Key Laboratory of Physical Chemistry of Solid Surfaces and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China;

    State Key Laboratory of Physical Chemistry of Solid Surfaces and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China;

    State Key Laboratory of Physical Chemistry of Solid Surfaces and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China;

    State Key Laboratory of Physical Chemistry of Solid Surfaces and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China;

    State Key Laboratory of Physical Chemistry of Solid Surfaces and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China;

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  • 原文格式 PDF
  • 正文语种 eng
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  • 入库时间 2022-08-18 03:15:57

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