Nitroxide-Substituted Nitronyl Nitroxide and Iminonitroxide

Shuichi Suzuki; Takanori Furui; Masato Kuratsu; Masatoshi Kozaki; Daisuke Shiomi; Kazunobu Sato; Takeji Takui; Keiji Okada

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Nitroxide-Substituted Nitronyl Nitroxide and Iminonitroxide

机译：一氧化氮取代的一氧化氮和亚氨基氧化氮

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We report on the highly compact nitroxide-substituted nitronyl nitroxide 1 and iminonitroxide 2; they have isoelectronic structures with trimethylenemethane. These diradicals are stable under aerated conditions at room temperature and have large positive exchange interactions: J/k_B = +390 K (H = -2JS_(1/2)·S_(1/2)) for 1 and j/k_B≈ +550 K for 2.

机译：我们报道了高度致密的一氧化氮取代的硝酰基硝基氧1和亚氨基硝基氧2；它们与三亚甲基甲烷具有等电子结构。这些双自由基在通风条件下于室温下稳定，并具有较大的正交换相互作用：J / k_B = +390 K（H = -2JS_（1/2）·S_（1/2））对于1和j /k_B≈+ 550 K用于2。

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《Journal of the American Chemical Society》 |2010年第45期|p.15908-15910|共3页
作者
Shuichi Suzuki; Takanori Furui; Masato Kuratsu; Masatoshi Kozaki; Daisuke Shiomi; Kazunobu Sato; Takeji Takui; Keiji Okada;
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作者单位

Department of Chemistry, Graduate School of Science, Osaka City University, Sugimoto Sumiyoshi-ku, Osaka 558-8585, Japan;

Department of Chemistry, Graduate School of Science, Osaka City University, Sugimoto Sumiyoshi-ku, Osaka 558-8585, Japan;

Department of Chemistry, Graduate School of Science, Osaka City University, Sugimoto Sumiyoshi-ku, Osaka 558-8585, Japan;

Department of Chemistry, Graduate School of Science, Osaka City University, Sugimoto Sumiyoshi-ku, Osaka 558-8585, Japan;

Department of Chemistry, Graduate School of Science, Osaka City University, Sugimoto Sumiyoshi-ku, Osaka 558-8585, Japan;

Department of Chemistry, Graduate School of Science, Osaka City University, Sugimoto Sumiyoshi-ku, Osaka 558-8585, Japan;

Department of Chemistry, Graduate School of Science, Osaka City University, Sugimoto Sumiyoshi-ku, Osaka 558-8585, Japan;

Department of Chemistry, Graduate School of Science, Osaka City University, Sugimoto Sumiyoshi-ku, Osaka 558-8585, Japan;

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收录信息美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);美国《化学文摘》(CA);
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入库时间 2022-08-18 03:15:56

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1. Nitroxide-Substituted Nitronyl Nitroxide and Iminonitroxide [J] . Shuichi Suzuki Takanori Furui Masato Kuratsu Masatoshi Kozaki Daisuke Shiomi Kazunobu Sato Takeji Takui and Keiji Okada American Chemical Society . 2010,第45期

机译：一氧化氮取代的一氧化氮和亚氨基氧化氮
2. 1,3-Dipolar Cycloaddition of a Nitronyl Nitroxide-Substituted Alkyne to Heteroaromatic N-Imines [J] . Romanov Vasiliy, Vorobev Aleksey, Bagryanskaya Irina, Australian Journal of Chemistry: A Journal for the Publication of Original Research in All Branches of Chemistry . 2017,第12期

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3. A Stable Radical-Substituted Radical Cation with Strongly Ferromagnetic Interaction: Nitronyl Nitroxide-Substituted 5,10-Diphenyl-5,10-dihydrophenazine Radical Cation [J] . Shinsuke Hiraoka, Toshihiro Okamoto, Masatoshi Kozaki, Journal of the American Chemical Society . 2004,第1期

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4. A hydroxyl-containing nitronyl nitroxide radical and its Dy (III) complex: Structure and magnetic properties [C] . Peng Hu, Fengping Xiao, Xiange Wu, International Conference on Materials Science, Resource and Environmental Engineering . 2017

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5. Synthesis and characterization of annelated nitronyl nitroxides. [D] . Bowles, Steven E. 2005

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6. (Pyrrole-25-Diyl)-Bis(Nitronyl Nitroxide) and-Bis(Iminonitroxide): Specific Features of the Synthesis Structure and Magnetic Properties [O] . Evgeny Tretyakov, Anastasia Tkacheva, Galina Romanenko, 2020

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Nitroxide-Substituted Nitronyl Nitroxide and Iminonitroxide

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