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Electrochemical Quartz Crystal Microbalance (EQCM) Studies of Ions and Solvents Insertion into Highly Porous Activated Carbons

机译:离子和溶剂插入高多孔活性炭中的电化学石英晶体微天平(EQCM)研究

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摘要

Electrochemical quartz crystal microbalance (EQCM) technique provides a direct assessment to the behavior of electroadsorbed ions and solvent molecules confined in mi cropores of activated carbon electrodes in contact with practically important aprotic electrolyte solutions. The estimated value of the solvation number equal to 3 is evident for a partial desolvation of Li~+ cations when adsorbed in carbon micropores.
机译:电化学石英晶体微量天平(EQCM)技术可直接评估局限在活性炭电极与实际重要的非质子电解质溶液接触的电吸附离子和溶剂分子的行为。当吸附在碳微孔中时,Li〜+阳离子部分去溶剂化时,溶剂化数的估计值等于3。

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  • 来源
    《Journal of the American Chemical Society》 |2010年第38期|p.13220-13222|共3页
  • 作者单位

    Department of Chemistry, Bar-Ilan University, Ramat-Gan 52900, Israel;

    rnDepartment of Chemistry, Bar-Ilan University, Ramat-Gan 52900, Israel;

    rnDepartment of Chemistry, Bar-Ilan University, Ramat-Gan 52900, Israel;

    rnDepartment of Chemistry, Bar-Ilan University, Ramat-Gan 52900, Israel;

    rnDepartment of Chemistry, Bar-Ilan University, Ramat-Gan 52900, Israel;

    rnMax Planck Institute for Solid State Research, Heisenbergstr. 1, 70569 Stuttgart, Germany;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);美国《化学文摘》(CA);
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  • 正文语种 eng
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