Generic Postfunctionalization Route from Amino-Derived Metal-Organic Frameworks

摘要

The secondary building unit (SBU) approach for engineering of metal-organic frameworks (MOFs) with tunable pore sizes is very attractive for designing practical properties such as separation by molecular sieving and shape-selective catalysis. The conceptual approach used to increase the pore sizes of MOFs through the use of longer ligands has also been extended to the design of multifunctional MOFs bearing a functional group on the organic moiety.