Heterolytic Dissociation of Water Demonstrated by Crystal-to-Crystal Core Interconversion from (μ-Oxo)divanadium to Bis(μ-hydroxo)divanadium Substituted Polyoxometalates

摘要

The heterolytic dissociation of water with the previously unknown four-coordinated syn-linear ($1-oxo)-divanadium core to form the five-coordinated bis($1-hydroxo)-divanadium core was confirmed by a crystal-to-crystal transformation.