Catalytic Functionalization of Methyl Group on Silicon: Iridium- Catalyzed C(sp~3)-H Borylation of Methylchlorosilanes

Toshimichi Ohmura; Takeru Torigoe; Michinori Suginome

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Catalytic Functionalization of Methyl Group on Silicon: Iridium- Catalyzed C(sp~3)-H Borylation of Methylchlorosilanes

机译：硅上甲基的催化功能化：铱催化甲基氯硅烷的C（sp〜3）-H硼化

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摘要

A methyl group of methylchlorosilanes undergoes C-H borylation in an iridium-catalyzed reaction with bis(pinacolato)diboron in cyclohexane at 80 ℃, giving (borylmethyl)chlorosilanes selectively.

机译：甲基氯硅烷的甲基在铱催化下与双（频哪醇）二硼在环己烷中于80℃反应，经C-H硼化，选择性生成（硼甲基）氯硅烷。

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来源
《Journal of the American Chemical Society》 |2012年第42期|17416-17419|共4页
作者
Toshimichi Ohmura; Takeru Torigoe; Michinori Suginome;
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作者单位

Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura,Nishikyo-ku, Kyoto 615-8510, Japan;

Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura,Nishikyo-ku, Kyoto 615-8510, Japan;

Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura,Nishikyo-ku, Kyoto 615-8510, Japan;

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收录信息美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);美国《化学文摘》(CA);
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入库时间 2022-08-18 03:13:39

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1. Functionalization of tetraorganosilanes and permethyloligosilanes at a methyl group on silicon via iridium-catalyzed C(sp3)-H borylation [J] . Ohmura T., Torigoe T., Suginome M. Organometallics . 2013,第21期

机译：通过铱催化的C（sp3）-H硼化作用在硅上的甲基上官能化四有机硅烷和过甲基低聚硅烷
2. A (Borylmethyl)silane Bearing Three Hydrolyzable Groups on Silicon: Synthesis via Iridium-Catalyzed C(sp(3))-H Borylation and Conversion to Functionalized Siloxanes [J] . Ohmura Toshimichi, Sasaki Ikuo, Torigoe Takeru, Organometallics . 2016,第11期

机译：在硅上带有三个可水解基团的（（甲酰基甲基）硅烷）：通过铱催化的C（sp（3））-H硼化反应合成并转化为官能化硅氧烷
3. A simple synthesis of functionalized 3-methyl-1-pyridinyl-1H-imidazolium salts as bidentate N-heterocycIic-carbene precursors and their application in Ir-catalyzed arene borylation [J] . Martin Peters, Rolf Breinbauer Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2010,第50期

机译：作为双齿N-杂环卡宾前体的功能化3-甲基-1-吡啶基-1H-咪唑鎓盐的简单合成及其在Ir催化的芳烃硼化中的应用
4. Direct 4’-substitution of planar-chiral terpyridine via iridium- catalyzed C-H borylation [C] . Mamoru Nakajima, Nobuhiro Kanomata 日本化学会春季年会講演予稿集 . 2018

机译：通过铱催化的C-H促进平坦4'替代Planar-Chiral Terpyridine
5. Effects of zinc and tin promoters on the copper-catalyzed conversion of silicon to methylchlorosilanes. [D] . Wessel, Timothy Jon. 1992

机译：锌和锡促进剂对铜催化的硅到甲基氯硅烷转化的影响。
6. Mechanism reactivity and selectivity of the iridium-catalyzed C(sp3)–H borylation of chlorosilanes [O] . Genping Huang, Marcin Kalek, Rong-Zhen Liao, 2015

机译：铱催化氯硅烷的C（sp3）–H硼化反应的机理反应性和选择性
7. Pd(II) Complexes with Chelating Phosphinoferrocene Diaminocarbene Ligands: Synthesis, Characterization, and Catalytic Use in Pd-Catalyzed Borylation of Aryl Bromides [O] . -1

机译：PD（II）配合物，螯合磷腈二苯甲苯配体：合成，表征和催化用途在PD催化芳基溴化硼酸化上

Catalytic Functionalization of Methyl Group on Silicon: Iridium- Catalyzed C(sp~3)-H Borylation of Methylchlorosilanes

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