Probing Solvation in Ionic Liquids via the Electrochemistry of the DPPH Radical

Alasdair W. Taylor; Simon Puttick; Peter Licence

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Probing Solvation in Ionic Liquids via the Electrochemistry of the DPPH Radical

机译：通过DPPH自由基的电化学探测离子液体中的溶剂

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The electrochemistry of the radical species 2,2-diphenyl-1-picrylhydrazyl, DPPH, has been studied in a range of common ionic liquids and its voltammetric response found to vary with the choice of anion. The trend observed is used to provide a relative Lewis basicity scale of nine ionic liquids commonly used as solvents.

机译：已经在一系列常见的离子液体中研究了自由基物质2,2-二苯基-1-吡啶并肼，DPPH的电化学，发现其伏安响应随阴离子的选择而变化。观察到的趋势用于提供通常用作溶剂的九种离子液体的相对路易斯碱度标度。

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来源
《Journal of the American Chemical Society》 |2012年第38期|p.15636-15639|共4页
作者
Alasdair W. Taylor; Simon Puttick; Peter Licence;
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作者单位

School of Chemistry, The University of Nottingham, Nottingham NG7 2RD, United Kingdom;

School of Chemistry, The University of Nottingham, Nottingham NG7 2RD, United Kingdom;

School of Chemistry, The University of Nottingham, Nottingham NG7 2RD, United Kingdom;

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收录信息美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);美国《化学文摘》(CA);
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入库时间 2022-08-18 03:13:39

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Probing Solvation in Ionic Liquids via the Electrochemistry of the DPPH Radical

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