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Densities and Kinematic Viscosities of Ten Binary Liquid Regular Solutions at 308.15 and 313.15 K

机译:308.15和313.15 K下十种二元液体常规溶液的密度和运动粘度

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The densities and kinematic viscosities of 10 binary regular solutions were measured over the entire composition range at 308.15 and 313.15 K. The excess volumes of mixing, absolute viscosities and viscosity deviations were calculated from the experimental data. The viscosity deviations were found to be negative for eight systems. For the two systems, heptane + octane and toluene + ethylbenzene, the viscosity deviations are scattered around zero. The data reported herein were used to examine the predictive capabilities of some viscosity-prediction models; namely, the predictive version of the McAllister model, the GC-UNIMOD model, the generalized corresponding states principle method, and the Allan and Teja correlation. The results of testing these models revealed that the McAllister model predicts the data much better than the other models and has the lowest absolute average deviation of 1.7%.
机译:在308.15和313.15 K的整个组成范围内,测量了10种二元常规溶液的密度和运动粘度。从实验数据中计算出过量的混合体积,绝对粘度和粘度偏差。发现八个系统的粘度偏差为负。对于庚烷+辛烷和甲苯+乙苯这两种体系,粘度偏差分散在零附近。本文报道的数据用于检验某些粘度预测模型的预测能力;分别是McAllister模型的预测版本,GC-UNIMOD模型,广义对应状态原理方法以及Allan和Teja相关性。测试这些模型的结果表明,McAllister模型比其他模型预测数据要好得多,并且绝对平均偏差最低,为1.7%。

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