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Study on Preparation and Property of Poly-Aminosilicone-Rare Earth Composite

机译:聚氨基硅氧烷-稀土复合材料的制备与性能研究

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The poly-aminosilicone-rare earth composite was prepared by poly-aminosilicone cross-linked with rare earth and active silanol. The thermal stability of the composites was studied by thermogravimetric analysis (TG). Force condition of the composites in electric field was analyzed and relative polarizability was derived. It is found that the composites containing different rare earth ions have different relative polarizability. The experiment results reveal that organosilicon materials with different electrical performance can be obtained by this way. Meanwhile, the absorption and flourescene spectrum of composites were also investigated. Compared to rare earth chloride, the spectrum properties of the composite are changed obviously. The possible reasons for these phenomena were discussed.
机译:通过与稀土和活性硅烷醇交联的聚氨基硅氧烷,制备了聚氨基硅氧烷稀土复合材料。通过热重分析(TG)研究了复合材料的热稳定性。分析了复合材料在电场中的受力状况,得出了相对极化率。发现含有不同稀土离子的复合物具有不同的相对极化率。实验结果表明,通过这种方法可以获得具有不同电性能的有机硅材料。同时,还研究了复合材料的吸收光谱和荧光光谱。与稀土氯化物相比,复合材料的光谱性质发生了明显变化。讨论了这些现象的可能原因。

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