Study on Poly(ferrocenylsilane) and Its Promotive Effect to Decomposition of Ammonium Perchlorate

摘要

SOLID propellant is one of the most significant ingredients used in rockets. The burning rate of propellant is a vital parameter for rocket design. A promising method to enhance the burning rate of propellants is to use burning-rate promoters (BRPs). BRPs have become increasingly important and are receiving more attention recently due to their successful use in solid propellant burning-rate enhancement. Generally, there are several kinds of BRPs; transition metal oxides, nanometal particles, metal chelate, ferrocene, and its derivatives. Transition metal oxide BRPs are cheap, but the burning-rate improvement of propellant is limited. The addition of nanometal particles can enhance the burning rate because nanometal particles have large specific surface areas and higher surface energy. However, nanometal particles are difficult to disperse well and passivation is needed for their surface to prevent spontaneous combustion in air [ 1 ]. Organic metal chelate BRPs, such as copper organic chelate and Plumbum iron double metal chelate, can greatly enhance the burning rate due to their good dispersion in propellants. Ferrocene and its derivatives have attracted much attention for their fascinating properties as BRPs [2]. They have been widely used in composite propellant, especially to enhance the burning rate of butyl hydroxide propellant, which contains ammonium perchlorate (AP) and aluminum powder. When ferrocene and its derivatives are used as BRPs, they are easy to migrate during storage. This migration affects their application in propellants. In this Note, we explore the possibility of using a series of poly (ferrocenylsilanes) with high molecular weights as BRPs.