Effect of solvents and solvent mixtures on intercalation/de-intercalation behaviour of Li~+ and CLO_4~- ions in polypropylene-graphite

摘要

The intercalation of Li~+ and CIO_4 ions in polypropylene-graphite composite electrodes in different single solvents and 1:1 binary solvent mixtures is studied by leans of cyclic voltammetry and scanning electron microscopy. The intercalation/de-intercalation efficiency as a potential dual-intercalation battery electrode for cationic intercalation (positive electrode) is found to be generally lower than that for anionic intercalation in most of the solvents 1:1 solvent mixtures do not enhance intercalation/de-intercalation efficiency significantly beyond the values found in a single solvent. The mixed-solvent system leads, however, to less co-solvent intercalation and graphite exfoliation, and hence better cycle-life as a potential battery electrode.