AC impedance diagnosis of a 500 W PEM fuel cell stack. Part II: Individual cell impedance

摘要

AC impedance or electrochemical impedance spectroscopy (EIS) has been demonstrated to be a powerful technique for characterizing and evaluating fuel cells. In this work, as an extension of our previous study on the stack impedance of a 500 W PEM fuel cell, we report the AC impedance studies on individual cells of the same fuel cell stack. The EIS of the stack with an active area of 280 cm~2 was measured at currents from 10 to 210 A in steps of 20 A using the combination of a FuelCon test station, a TDI loadbank and a Solartron 1260 Frequency Response Analyzer. Measurement of the individual cell EIS was carried out with the help of a rotary switch unit made in our lab. Two methods (floating mode and grounded mode) were utilized for measuring the impedance spectroscopy of the individual cells. The results show that both methods are applicable to individual cells. The results also indicate a good agreement between the total Ohmic loss in the stack and the combined Ohmic losses of the individual cells.