Fabrication of protic ionic liquid/sulfonated polyimide composite membranes for non-humidified fuel cells

摘要

We have demonstrated that a protic ionic liquid, diethylmethylammonium trifluoromethanesulfonate ([dema][TfO]) functions as a proton conductor and is suitable for use as an electrolyte in H_2/O_2 fuel cells, which can be operated at temperatures higher than 100 ℃ under non-humidified conditions. In this study, in order to fabricate a polymer electrolyte fuel cell, matrix polymers for [dema][TfO] are explored and sulfonated polyimides (SPI), in which the sulfonic acid groups are in diethylmethylammonium form, are found to be highly compatible with [dema][TfO]. Polymer electrolyte membranes for non-humidified fuel cells are prepared by the solvent casting method using SPI and [dema][TfO]. The SPI, with an ion exchange capacity of 2.27 meq g~(-1), can retain four times its own weight of [dema][TfO] and produces uniform, tough, and transparent composite membranes. The composite membranes have good thermal stability (>300 ℃) and ionic conductivity (>10~(-2) cm~(-1) at 120 ℃ when the [dema][TfO] content is higher than 67 wt%) under anhydrous conditions. In the H_2/O_2 fuel cell operation using a composite membrane without humidification, a current density higher than 240mA cm~(-2) is achieved with a maximum power density of 100 mW cm~(-2) at 80 ℃.