首页> 外文期刊>Journal of power sources >Cyclic silicon-nitrogen-silicon core derived silylamido-magnesium compounds for magnesium-battery electrolytes with improved oxidation stability
【24h】

Cyclic silicon-nitrogen-silicon core derived silylamido-magnesium compounds for magnesium-battery electrolytes with improved oxidation stability

机译:环状硅-氮-硅核衍生的甲硅烷基-镁化合物,用于镁电池电解质,具有改善的氧化稳定性

获取原文
获取原文并翻译 | 示例
获取外文期刊封面目录资料

摘要

Use of a silylamido-magnesium chloride and a magnesium bis-silylamide where the Si-N-Si core is crafted in a cyclic structure, toward magnesium battery application is demonstrated. Reaction between prepared silylamido magnesium compounds and a Lewis acid in tetrahydrofuran solvent furnishes the desired electrolytes. Embedding the Si-N-Si core into cyclic structure enhances the oxidation potentials of the 'in situ' electrolytes (without any purification) against Mg/Mg2+ compare to the acyclic analogue. Theoretical calculation provides insight into the ionic species present in the electrolyte systems. (C) 2015 Elsevier B.V. All rights reserved.
机译:已经说明了将Si-N-Si核制成环状结构的甲硅烷基氨基氯化镁和双甲硅烷基镁镁在镁电池中的应用。在四氢呋喃溶剂中,制备的甲硅烷基氨基镁化合物与路易斯酸之间的反应提供了所需的电解质。与无环类似物相比,将Si-N-Si核嵌入环状结构可增强“原位”电解质(无需任何纯化)对Mg / Mg2 +的氧化电位。理论计算可深入了解电解质系统中存在的离子种类。 (C)2015 Elsevier B.V.保留所有权利。

著录项

  • 来源
    《Journal of power sources》 |2015年第30期|551-555|共5页
  • 作者单位

    Samsung Elect Co, Samsung Adv Inst Technol, Energy Lab, Suwon 443803, Gyeonggi Do, South Korea;

    Samsung Elect Co, Samsung Adv Inst Technol, Energy Lab, Suwon 443803, Gyeonggi Do, South Korea;

    Samsung Elect Co, Samsung Adv Inst Technol, Energy Lab, Suwon 443803, Gyeonggi Do, South Korea;

    Samsung Elect Co, Samsung Adv Inst Technol, Energy Lab, Suwon 443803, Gyeonggi Do, South Korea;

    Samsung Elect Co, Samsung Adv Inst Technol, Energy Lab, Suwon 443803, Gyeonggi Do, South Korea;

    Samsung Elect Co, Samsung Adv Inst Technol, Energy Lab, Suwon 443803, Gyeonggi Do, South Korea;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    Cyclic; Silylamido-magnesium; Transmetallation; Anionic complex; Oxidation stability;

    机译:环状;硅铝酰胺-镁;金属转移作用;阴离子络合物;氧化稳定性;

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱:kefu@zhangqiaokeyan.com

京公网安备:11010802029741号 ICP备案号:京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有
  • 客服微信

  • 服务号