Magnesium substitution to improve the electrochemical performance of layered Li2MnO3 positive-electrode material

摘要

Li2MnO3 has received lots of attention due to its large theoretical capacity. However, its application is obstructed by low practical capacity and poor cycling stability. Here, a new tactic of magnesium substitution for partial lithium to improve the electrochemical performance of Li2MnO3 by a traditional solid state reaction is presented. Sample with only 1% magnesium content delivers a large initial discharge capacity of 307.5 mAh g(-1) which is much superior than the 241.9 mAh g(-1) of pristine Li2MnO3. The cycling performance also get improved that the capacity retention is 84.5% for Li1.98Mg0.01MnO3 but only 77.7% for pristine counterpart after 30 cycles at 0.1 C. Moreover, the effective suppression of voltage decay has been achieved because of improved kinetic properties and leads to a tremendous progress in the energy density which is as much as 944 Wh kg(-1) for Li1.98Mg0.01MnO3 compared with 747.1 Wh kg-1 of Li2MnO3. These achievements attained by Mg-doping make Li2MnO3 a promising positive-electrode material for the next generation of lithium ion batteries. (C) 2016 Elsevier B.V. All rights reserved.