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Ionic Liquid-Immobilized Quinuclidine-Catalyzed Morita-Baylis-Hillman Reactions

机译:离子液体固定化奎尼丁催化的森田-贝利斯-希尔曼反应

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摘要

The ionic liquid-bound quinuclidine catalyzed Baylis-Hill-man reactions were investigated.The IL-supported catalyst showed equally good catalytic activity as compared with its nonimmobilized counterpart.The corresponding Baylis - Hillman adducts were obtained in moderate to high yields in all the cases tested.The IL-supported quinuclidine can be readily recovered and reused six times without significant loss of catalytic activity.
机译:研究了离子液体结合的奎宁环催化的Baylis-Hill-man反应,与非固定化催化剂相比,IL负载的催化剂表现出同样好的催化活性,在所有情况下均以中等至高收率获得了相应的Baylis-Hillman加合物。经IL负载的奎尼丁可轻松回收并重复使用六次,而不会显着降低催化活性。

著录项

  • 来源
    《The Journal of Organic Chemistry》 |2005年第6期|p.2338-2341|共4页
  • 作者单位

    Department of Chemistry and State Key Laboratory of Elemento-organic Chemistry,Nankai University,Tianjin 300071,China,and Center for Molecular Science,Institute of Chemistry,Chinese Academy of Sciences,Beijing 100080,China;

    Department of Chemistry and State Key Laboratory of Elemento-organic Chemistry,Nankai University,Tianjin 300071,China,and Center for Molecular Science,Institute of Chemistry,Chinese Academy of Sciences,Beijing 100080,China;

    Department of Chemistry and State Key Laboratory of Elemento-organic Chemistry,Nankai University,Tianjin 300071,China,and Center for Molecular Science,Institute of Chemistry,Chinese Academy of Sciences,Beijing 100080,China;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 有机化学;
  • 关键词

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