Synthesis of 1,10-N,N'-phenanthroline dioxides using HOF center dot CH3CN complex

摘要

[GRAPHICS]HOF-CH3CN, a very efficient oxygen-transfer agent, made readily from F-2, H2O, and CH3CN, was reacted with various 1,10-phenanthroline derivatives to form the corresponding N,N'-dioxides in good yields and short reaction times.