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Concise Asymmetric Total Synthesis of Obolactone

机译：简明不对称全合成内酯

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摘要

The first efficient asymmetric synthesis of obolactone 1 has been accomplished in 11 steps and with a 15% overall yield in which Brown's enantioselective allylation reactions and ring closing metathesis reaction are key steps.
机译：olactactone 1的第一个有效的不对称合成已经完成了11个步骤，总收率为15％，其中Brown的对映选择性烯丙基化反应和闭环复分解反应是关键步骤。

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  • 来源
    《The Journal of Organic Chemistry》 |2006年第7期|p.2918-2921|共4页
  • 作者

    Jiyong Zhang; Yang Li; Wenkuan Wang; Xuegong She; Xinfu Pan;

  • 作者单位

    Department of Chemistry,State Key Laboratory of Applied Organic Chemistry,Lanzhou University,Lanzhou 730000,People 's Republic of China,and State Key Laboratory for Oxo Synthesis and Selective Oxidation,Lanzhou Institute of Chemical Physics,Chinese A;

    Department of Chemistry,State Key Laboratory of Applied Organic Chemistry,Lanzhou University,Lanzhou 730000,People 's Republic of China,and State Key Laboratory for Oxo Synthesis and Selective Oxidation,Lanzhou Institute of Chemical Physics,Chinese A;

    Department of Chemistry,State Key Laboratory of Applied Organic Chemistry,Lanzhou University,Lanzhou 730000,People 's Republic of China,and State Key Laboratory for Oxo Synthesis and Selective Oxidation,Lanzhou Institute of Chemical Physics,Chinese A;

    Department of Chemistry,State Key Laboratory of Applied Organic Chemistry,Lanzhou University,Lanzhou 730000,People 's Republic of China,and State Key Laboratory for Oxo Synthesis and Selective Oxidation,Lanzhou Institute of Chemical Physics,Chinese A;

    Department of Chemistry,State Key Laboratory of Applied Organic Chemistry,Lanzhou University,Lanzhou 730000,People 's Republic of China,and State Key Laboratory for Oxo Synthesis and Selective Oxidation,Lanzhou Institute of Chemical Physics,Chinese A;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 有机化学;
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  • 入库时间 2022-08-18 00:02:44

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