Syntheses of Novel Chiral Sulfinamido Ligands and Their Applications in Diethylzinc Additions to Aldehydes

Zhiyan Huang; Hongshan Lai; Yong Qin

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Syntheses of Novel Chiral Sulfinamido Ligands and Their Applications in Diethylzinc Additions to Aldehydes

机译：新型手性亚磺酰胺基配体的合成及其在醛二乙基锌加成中的应用

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摘要

A novel class of sulfinamido alcohol ligands 1—6 was synthesized from (S)-tert-butanesulfinamide. These ligands showed excellent catalytic activities and enantiomeric selectivities in asymmetric additions of diethylziuc to aromatic aldehydes.

机译：由（S）-叔丁烷亚磺酰胺合成了一类新的亚磺酰胺基醇配体1-6。这些配体在向芳香族醛中不对称添加二乙基氧化锆时表现出出色的催化活性和对映异构体选择性。

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来源
《The Journal of Organic Chemistry》 |2007年第4期|p.1373-1378|共6页
作者
Zhiyan Huang; Hongshan Lai; Yong Qin;
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作者单位

Department of Chemistry of Medicinal Natural Products and Key Laboratory of Drug Targeting, West China School of Pharmacy, Sichuan University, Chengdu 610041, P. R. China;

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收录信息美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);美国《化学文摘》(CA);
原文格式 PDF
正文语种 eng
中图分类有机化学;
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入库时间 2022-08-18 00:02:13

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机译：手性BINOL衍生物的合成，晶体结构及其在对映选择性路易斯酸催化二乙基锌加成醛中的应用
2. Synthesis of a New Chiral Ligand, 6,6'-Dihydroxy-5,5'-Biquinoline (BIQOL) and Its Applications in the Asymmetric Addition of Diethylzinc to Aldehydes [J] . Yi-Xin Chen, Li-Wei Yang, Yue-Ming Li, Chirality: The pharmacological, biological, and chemical consequences of molecular asymmetry . 2000,第5a6期

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机译：化学酶法合成反式环己烷1,2-二胺的新型配体：在将二乙基锌对芳香醛对映选择性加成中的应用
4. Synthesis of Chiral Tridentate Ligands Embodying the Bispidine Framework and Their Application in the Enantioselective Addition of Diethylzinc to Aldehydes [C] . Yuecheng Zhang, Jingyuan Gao, Naiyue Shi, International Conference on Chemical, Material and Metallurgical Engineering . 2012

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6. Stereoselective Syntheses and Application of Chiral Bi- and Tridentate Ligands Derived from (+)-Sabinol [O] . Yerbolat Tashenov, Mathias Daniels, Koen Robeyns, 2018

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7. Syntheses of Novel Chiral Sulfinamido Ligands and Their Applications in Diethylzinc Additions to Aldehydes [O] . -1

机译：新型手性磺胺胺配体的合成及其在二乙基上的应用中的应用

Syntheses of Novel Chiral Sulfinamido Ligands and Their Applications in Diethylzinc Additions to Aldehydes

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