Direct and closed form analytical model for the prediction of reaction kinetic of EPDM accelerated sulphur vulcanization

摘要

A novel direct model with kinetic base for the prediction of the final vulcanization level of EPDM cured with sulphur is presented. The model bases on a preliminary characterization of rubber through standard rheometer tests and allows an accurate prediction of the crosslinking degree at both successive curing times and different controlled temperatures. Both the case of indefinite increase of the torque and reversion can be handled. The approach proposed bases on a previously presented exponential model, where a calibration of three kinetic constants at fixed temperature by means of non-linear least square fitting was required. Here the exponential model is superseded and kinetic constants are evaluated through simple closed form formulas. The applicability of the approach is immediate and makes the model extremely appealing when fast and reliable estimates of crosslinking density of cured EPDM are required. To show the capabilities of the approach proposed, a comprehensive comparison with both available experimental data and results obtained numerically with the exponential model for real compounds at different temperatures is finally provided.