Controllable synthesis and magnetic properties of Fe–Co alloy nanoparticles attached on carbon nanotubes

摘要

Fe–Co alloy nanoparticles with different size were attached on the carbon nanotubes through adjusting the ratio of the metal to carbon in the mixed solution of nitrate with Fe:Co = 1:1 (molar ratio) via wet chemistry. X-ray powder diffraction (XRD), transmission electron microscopy (TEM), high-resolution transmission electron microscopy (HRTEM) and energy-dispersive X-ray spectrometry (EDX) indicated that the Fe–Co alloy nanoparticles attached on the surface of carbon nanotubes has body-centered cubic (bcc) structure, with sizes in the range of 13–25 nm and in the shape of spheroids. Magnetization measurements indicated that both the coercivities and the saturation magnetizations altered with size changes of the Fe–Co alloy nanoparticles. The saturation magnetization decreases with decreasing the Fe–Co alloy nanoparticles’ sizes. A decrease in coercivity with increasing Fe–Co size together with a local maximum coercivity at size of ca. 15 nm is visible. A linear relationship between the inverse particle diameter and the coercivity was found for larger particles. These demonstrated that the chemical method here is promising for fabricating Fe–Co alloy nanoparticles coated on carbon nanotubes for magnetic storage applications.