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Cost-effective aegle marmelos extract-assisted synthesis of ZnFe_2O_4:Cu~(2+) NPs: photocatalytic and electrochemical sensor applications

机译:具有成本效益的Aegle Marmelos提取辅助合成ZnFe_2O_4:Cu〜(2+)NPS:光催化和电化学传感器应用

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摘要

In the reported work, Zn_xFe_2O_4:Cu_(1-x)~(2+) nanoparticle (CZF NPs) was successfully synthesized from fabrication of copper (Cu~(2+)) doped ZnFe_2O_4 NPs by a facile one-pot green (Aegle Marmelos extract) assisted combustion approach. The structural characterizations were investigated by specific spectral techniques; Powder X-Ray diffractometer (PXRD) confirms the formation of spinel cubic nanocrystalline structure with crystallite size in the range 20-25 nm. The porous with spongy like structure morphology was noticed by Scanning electron microscope (SEM). The photocatalytic performance of CZF NPs (7 mol%) was examined by observing their potential role in photodegradation of Rhodamine B (Rh-B) dye (94%) under irradiation of UV-Visible light. Electrochemical study was conducted by graphite assisted with CZF electrode paste in 0.1 M KC1 electrolyte and performed as an excellent mechanism of charge-discharge supercapacitor nature with high responses towards the electrochemical sensor action for Mifepristone-Misoprostol.
机译:在报道的工作中,通过铜(Cu〜(2+))掺杂的ZnFe_2O_4 NPS成功地合成了Zn_XFE_2O_4:Cu_(1-x)〜(2+)纳米颗粒(Cu〜(2+))掺杂ZnFe_2O_4 NPS(Aegle Marmelos提取物)辅助燃烧方法。通过特定光谱技术研究了结构特征;粉末X射线衍射仪(PXRD)证实尖晶石立方纳米晶体结构的形成,微晶尺寸在20-25nm的范围内。通过扫描电子显微镜(SEM)注意到具有海绵状结构形态的多孔。通过在紫外线可见光照射下观察罗丹明B(RH-B)染料(94%)的光降解中的潜在作用,检查CZF NPS(7mol%)的光催化性能。通过辅助CZF电极浆料的石墨进行电化学研究,在0.1M KCl电解质中辅助CZF电极浆料,并作为对米非代代酮 - 米索前列醇的电化学传感器作用的高响应进行电荷放电超级电容性的优异机制。

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  • 来源
    《Journal of materials science》 |2021年第20期|25234-25246|共13页
  • 作者单位

    Department of Chemistry East West Institute of Technology Bengaluru 560 091 India;

    Department of Chemistry SJB Institute of Technology Bengaluru 560 060 India;

    Department of Chemistry SJB Institute of Technology Bengaluru 560 060 India;

    Department of Chemistry SJB Institute of Technology Bengaluru 560 060 India;

    Department of Chemistry SJB Institute of Technology Bengaluru 560 060 India;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);
  • 原文格式 PDF
  • 正文语种 eng
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