Synthesis of highly environmental stable copper-silver core-shell nanoparticles for direct writing flexible electronics

摘要

In this study, Cu@Ag core-shell nanoparticles (NPs) with highly environmental stability were synthesized successfully by combining the NaBH_4 reduction method with the transmetallation reaction, and the Cu@Ag nano-ink was prepared for direct writing flexible electronics. The structure, component, thermal stability and oxidation resistance of Cu NPs and Cu@Ag core-shell nanoparticles were characterized and discussed systematically. The results showed that Cu NPs could be obtained via the reduction of Cu~(2+) ions by using cetyltrimethylammonium bromide (CTAB) as a dispersing agent under an excess of sodium hydroxide (NaOH) and sodium borohydride (NaBH_4) in aqueous solution. And the Cu@Ag core-shell nanoparticles with uniform Ag shell and Cu core can be fabricated with the transmetallation reaction that Ag~+ ions were reduced by the copper atoms on the surface of Cu NPs at pH 7, and the Cu core were kept from oxidation from the Ag shell. Besides, Cu@Ag nano ink were fabricated by dispersing Cu@Ag core-shell nanoparticles in ethylene glycol, and Cu@Ag conductive pattern were directly drawn on ordinary photo paper using a roller pen filled with 30 wt% Cu@Ag nano ink. The electrical resistivity of the conductive Cu@Ag pattern obtained from the nano ink was as low as 13.8 μΩ cm~(−1) due to the continuous interconnections between the nanoparticles established when thermal sintered at 150 °C for 1 h under N_2. When the conductive wires of a lamp were connected to the two ends of the written conductive line, the lamp was illuminated immediately. It demonstrated that the complicated Cu@Ag nano-ink pattern had very good conductivity and applicability. This work provides an effective approach to prepare Cu@Ag core-shell nano-ink for direct writing flexible electronics.