Low-temperature reducible particle-free screen-printable silver ink for the fabrication of high conductive electrodes

摘要

In this contribution, screen printing of aqueous based particle-free silver ink is addressed using combustion chemistry, where inks embody a redox mixture of silver nitrate and citric acid in the presence of a binder, sodium-carboxymethylcellulose. The exothermic reaction at ~ 176 ℃ results in the formation of pure silver. Screen-printing process is optimized for three different silver loadings (14%, 18% and 22%) in ink. In depth rheological study of the inks reveals thixotropic nature and the ink with 18% of silver possessing a viscosity of 328 Pa .s has a recovery rate of 84% at 110 s with a shear rate of 1 s~(-1). The deposited silver films (~3 urn thick) on both rigid-glass and flexible-polyamide substrates have shown an electrical conductivity of 4.2 × 10~6 S m~(-1) and 2.6 × 10~6 S m~(-1) respectively. Film adhesion on glass substrates categorized under 3B as per ASTM D-3359. Present screen-printed silver films find their application as a gate electrode in thin film transistors (TFTs). The TFTs comprising of indium zinc tin oxide-semiconductor and sodium β -alumina dielectric with screen-printed silver as a gate electrode exhibited the saturation mobility, on:off ratio and threshold voltage of 0.88 cm2 V~(-1) s~(-1), 10~2 and~0.3 V respectively.