Influence of oxygen impurity contained in nitrogen gas on the reactions of chromium with nitrogen

摘要

In this research, the influences of the oxygen impurity contained in the commercially available nitrogen gas on the reactions of chromium pellets with nitrogen were investigated in the temperature range 600-1350 °C. A small amount of oxygen competed with the majority N2 to react with chromium in the annealing process. Analyzing the in situ oxygen partial pressure changes during annealing proved that the dissolution of oxygen in Cr and/or resultant Cr_xN (CrN or Cr_2N) was exothermic and the solubility decreased with increasing temperature. It was found that the oxygen partial pressure decreased drastically to about 10~(-22) atm when specimens were annealed at 600 deg C compared to a mere 10~(-5) atm for a blank test, while its value increased with temperature. The oxidation involved simultaneous dissolution of oxygen in specimens and formation of oxide scale. Moreover, comparing the aforementioned results with those obtained from additional annealing experiments preformed in argon gas showed that the formation of Cr_2O_3 might stem mainly from oxidation of the resultant nitrides instead of the metallic chromium.