Synthesis, structural investigation and magnetic properties of Zn~(2+) substituted cobalt ferrite nanoparticles prepared by the sol-gel auto-combustion technique

摘要

Structural morphology and magnetic properties of the Co_(1-x)Zn_xFe_2O_4 (0.0 ≤ x ≥ 1.0) spinel ferrite system synthesized by the sol-gel auto-combustion technique using nitrates of respective metal ions have been studied. The ratio of metal nitrates to citric acid was taken at 1:3. The as prepared powder of cobalt zinc ferrite was sintered at 600 ℃ for 12 h after TG/DTA thermal studies. Compositional stoichiometry was confirmed by energy dispersive analysis of the X-ray (EDAX) technique. Single phase cubic spinel structure of Co-Zn nanoparticles was confirmed by XRD data. The average crystallite size (t), lattice constant (a) and other structural parameters of zinc substituted cobalt ferrite nanoparticles were calculated from XRD followed by SEM and FTIR. It is observed that the sol-gel auto-combustion technique has many advantages for the synthesis of technologically applicable Co-Zn ferrite nanoparticles. The present investigation clearly shows the effect of the synthesis method and possible relation between magnetic properties and microstructure of the prepared samples. Increase in nonmagnetic Zn~(2+) content in cobalt ferrite nanoparticles is followed by decrease in n_B, M_s and other magnetic parameters. Squareness ratio for the Co-ferrite was 1.096 at room temperature.