A study on impact of zinc substitution on magneto-optic properties of manganese ferrite nanoferrofluids

摘要

Highlights • Mn 1-x Zn x Fe2O4 nanoparticles were successfully prepared by co-precipitation method. • Phase analysis confirms the cubic spinel structure. • Crystallite size and lattice constant decreases with increasing zinc concentration. • Magnetic properties are decreasing with increasing zinc concentration. • Faraday rotation and Verdet constant decreases with increasing zinc substitution. Abstract Mn 1-x Zn x Fe2O4 nanoparticles (x =0.1, 0.3, 0.5, 0.7 and 0.9) were synthesized using chemical co-precipitation method. X-ray diffraction (XRD) analysis confirmed the cubic spinel structure of synthesized nanoparticles. The crystallite size and lattice parameter were found to decrease with increase in zinc substitution. Surface morphology by scanning electron microscope (SEM) and energy dispersive analysis of X-ray (EDAX) confirmed the presence of substituted metal ions in all the samples. Magnetic parameters at room temperature using vibrating sample magnetometer (VSM) are found to decrease with increasing zinc substitution. Faraday rotation of Mn 1-x Zn x Fe2O4 nanoferrofluids is found to vary with zinc substitution under applied magnetic field. Verdet constant obtained from Faraday rotation are found to vary from 5.35 to 2.71deg./Tcm with zinc substitution.