Enhanced Specific Heat Capacity of Molten Salt-Based Carbon Nanotubes Nanomaterials

摘要

This study aims to investigate the specific heat capacity of a carbonate salt eutectic-based multiwalled carbon nanomaterial (or high temperature nanofiuids). The specific heat capacity of the nanomaterials was measured both in solid and liquid phase using a differential scanning calorimetry (DSC). The effect of the carbon nanotube (CNT) concentrations on the specific heat capacity was examined in this study. The carbonate molten salt eutectic with a high melting point around 490 ℃, which consists of lithium carbonate of 62% and potassium carbonate of 38% by the molar ratio, was used as a base material. Multiwalled CNTs were dispersed in the carbonate salt eutectic. A surfactant, sodium dodecyl sulfate (SDS) was utilized to obtain homogeneous dispersion of CNT into the eutectic. Four different concentrations (0.1, 0.5, 1, and 5wt.%) of CNT were employed to explore the specific heat capacity enhancement of the nanomaterials as the concentrations of the nanotubes varies. In result, it was observed that the specific heat capacity was enhanced by doping with the nanotubes in both solid and liquid phase. Additionally, the enhancements in the specific heat capacity were increased with increase of the CNT concentration. In order to check the uniformity of dispersion of the nanotubes in the salt, scanning electron microscopy (SEM) images were obtained for pre-DSC and post-DSC samples. Finally, the specific heat capacity results measured in present study were compared with the theoretical prediction.