Dependence of humidified air plasma discharge performance in commercial honeycomb monoliths on the configuration and key parameters of the reactor

摘要

The effect of the reactor configuration and several key parameters such as the gas temperature, humidity, and flow rate on the corona discharge plasma in honeycomb monoliths was investigated. The AC corona dischargebased plasma reactor consisted of two parallel electrodes (perforated disk/wire-mesh) placed at both ends of the honeycomb monolith. Although the wire-mesh electrode offers increased sharpness, the perforated disk electrode, where the corona discharge started at the sharp edges of the holes, produced more discharge power because of the larger effective electrode area. Loading a small amount of metal onto the monolith was found to increase the discharge power significantly. Coating the monolith with a zeolite such as ZSM-5 (Si/Al: 23.9) led to a decrease in the discharge power because of its hydrophobic nature and large surface area. The result also revealed that the operating temperature, the humidity of the feed gas, and the gas velocity were key factors affecting the discharge performance. The discharge power was inversely proportional to the temperature. On the other hand, the use of a high-velocity feed gas with high water vapor content was found to be particularly advantageous for obtaining high discharge power.