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Obtaining the isosteric sorption heat directly by sorption isotherm equations

机译:通过吸附等温线方程直接获得等规吸附热

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摘要

The latent heat of vaporization of water in foodstuffs is an important factor for the design of drying equipments. The thermal properties can be calculated by equations that are derived directly from isotherm equations by the Clausius-Clapeyron thermody-namic theory. The sorption isosteric heat equation can be expressed as a function of temperature and moisture content. The sorption isosteric heat computed from the water activity (A_w) sorption isosteric model developed in this study showed good agreements with the values calculated by the Clausius-Clapeyron equation or from calorimetric method. As the A_w model had the better fitting performance, the sorption isosteric heat values calculated from the water activity sorption isosteric model were more close to the sorption isosteric heat values obtained from other methods.
机译:食品中水汽化的潜热是干燥设备设计的重要因素。可以通过由克劳修斯-克拉佩隆热力学自然理论直接从等温方程导出的方程来计算热性能。吸附等排热方程可以表示为温度和水分含量的函数。根据本研究开发的水分活度(A_w)吸附等构模型计算出的吸附等构热与通过Clausius-Clapeyron方程或量热法计算的值显示出良好的一致性。由于A_w模型具有更好的拟合性能,因此从水活度吸附等规线模型计算出的吸附等温线值更接近于其他方法获得的吸附等温线值。

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