Ferrate(Ⅵ): A green chemical for the oxidation of cyanide in aqueous/waste solutions

摘要

The higher oxidation state of iron, i.e. Fe(Ⅵ), was employed for the oxidation of the important toxic ion cyanide in aqueous/waste waters. Cyanide was oxidized to cyanate, which is 1,000 times less toxic than cyanide, and can often be accepted for its ultimate disposal. It was noted that Fe(Ⅵ) is a very powerful oxidizing agent, and can oxidize most of the cyanide within a few minutes, ca 5 minutes, of contact. The extent of the reduction of Fe(Ⅵ) was obtained using the UV-Visible measurements. Further, the UV-Visible data was used to explain the reaction kinetics involved in the redox reaction between ferrate(Ⅵ) and cyanide. The pseudo-first-order rate constant was calculated by maintaining the cyanide concentration in excess, with the overall second order rate constant values obtained for initial Fe(Ⅵ) concentrations of 1.0 and 0.1 mmol/L. The oxidation of cyanide was again confirmed using a cyanide probe. Fe(Ⅵ) was further employed for its possible application in the treatment of industrial wastewaters containing cyanide, along with some heavy metals, such as those obtained from electroplating industries.