Structural and luminescent properties of Mg_4Nb_2O_9 nanocrystals

摘要

Synthesis and luminescence properties of Mg_4Nb_2O_9 nanocrystals by citric gel process were investigated in this work. The samples were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), high-resolution transmission electron microscopy (HRTEM), and photoluminescence (PL). The excitation band at about 241 and 341 nm originates from the regular and defect octahedra group [NbO_6]~(7-). The room-temperature PL spectra under 241 and 341 nm excitations show a broad violet and a very strong emission peaks located at 390 and 402 nm, respectively.