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Sustainable lignin to enhance asphalt binder oxidative aging properties and mix properties

机译:可持续的木质素可增强沥青粘合剂的氧化老化性能和混合性能

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摘要

Using sustainable, renewable substances that can be locally-sourced instead of petroleum-based asphalt binders would be better for our environment. Replacing a small portion (maximum of 6%) of asphalt binder with three different types of lignin was investigated to determine its effects on aged and unaged asphalt binder and mix. Commercially available Kraft lignin, lignin precipitated from black liquor in the laboratory, I ignin produced from rice hulls in the laboratory using a deep eutectic solvent, and a standard asphalt binder (control) were evaluated. Lignin improved the high temperature performance grade. All lignin-modified binders showed higher strain tolerance than unmodified binders in strain sweep tests. Lignin precipitated from black liquor and lignin produced from rice hulls improved the long-term aging index. Rutting, cracking, and moisture damage susceptibility tests were performed on an asphalt mix prepared with 6% lignin precipitated from black liquor asphalt binder. Improved rutting resistance was observed from the lignin-modified asphalt mix, without sacrificing moisture-induced damage resistance. Better cracking resistance with respect to increased flexibility index was observed according to the semi-circular bend test. Replacing petroleum-based binder with up to 6% of lignin precipitated from black liquor is practicable for hot mix asphalt, and may be feasible in the lower temperature warm mix asphalt process. (C) 2019 Elsevier Ltd. All rights reserved.
机译:使用可以本地采购的可持续可再生物质代替石油基沥青粘合剂,对我们的环境会更好。研究了用三种不同类型的木质素代替一小部分(最多6%)的沥青粘合剂,以确定其对老化和未老化的沥青粘合剂及其混合物的影响。评估了市售的牛皮纸木质素,实验室黑液中沉淀的木质素,实验室中使用深共熔溶剂从稻壳获得的木质素,以及标准沥青粘合剂(对照品)。木质素提高了高温性能等级。在应变扫描测试中,所有木质素改性的粘合剂均比未改性的粘合剂具有更高的应变耐受性。黑液中沉淀出的木质素和稻壳产生的木质素改善了长期老化指数。对用从黑液沥青粘合剂中沉淀出的6%木质素制备的沥青混合料进行车辙,开裂和湿气损害敏感性测试。从木质素改性的沥青混合料中观察到改善的耐车辙性,而没有牺牲水分引起的耐破坏性。根据半圆形弯曲试验,观察到相对于增加的挠性指数而言更好的抗裂性。用从黑液中沉淀出的木质素最多替代6%的石油基粘合剂对于热拌沥青是可行的,并且在较低温度的温拌沥青过程中是可行的。 (C)2019 Elsevier Ltd.保留所有权利。

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