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A method for increasing the surface area of perovskite-type oxides

机译:一种增加钙钛矿型氧化物表面积的方法

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A method based on hydrothermal treatments is described for increasing the surface area of sintered ABO_3-type perovskite oxides. Influence of hydrothermal treatments, such as water treatment at 125-300deg.C under autogeneous pressure and steam treatment at 350-800deg.C, to low surface area 9or sintered) LaCoo_3 and LaMnO_3 perovskite oxides on their surface properties (viz. Surface area, crystal size and morphology and surface La/(Co or Mn) ratio) and also catalytic activity in complete combustion of methane at different temperatures (450-600deg.C) has been thoroughly investigated. The hydrothermal treatments result in the activation of the perovskite oxides by increasing their surface area very markedly.
机译:描述了一种基于水热处理的方法,用于增加烧结的ABO_3型钙钛矿氧化物的表面积。水热处理,例如在自生压力下于125-300℃下进行水处理和在350-800℃下进行蒸汽处理,对低表面积9或烧结的LaCoo_3和LaMnO_3钙钛矿氧化物对其表面性质(即表面积,晶体的大小和形态,表面La /(Co或Mn)之比)以及在不同温度(450-600°C)下甲烷完全燃烧中的催化活性已被彻底研究。水热处理通过非常显着地增加钙钛矿氧化物的表面积而导致钙钛矿氧化物的活化。

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