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Nanoscale studies of domain wall motion in epitaxial ferroelectric thin films

机译:外延铁电薄膜中畴壁运动的纳米尺度研究

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摘要

Atomic force microscopy was used to investigate ferroelectric switching and nanoscale domain dynamics in epitaxial Pb(Zr_(0.2)Ti_(0.8))O_3 thin films. Measurements of the writing time dependence of domain size reveal a two-step process in which nucleation is followed by radial domain growth. During this growth, the domain wall velocity exhibits a υ ∝ exp-(1/E)~μ dependence on the electric field, characteristic of a creep process. The domain wall motion was analyzed both in the context of stochastic nucleation in a periodic potential as well as the canonical creep motion of an elastic manifold in a disorder potential. The dimensionality of the films suggests that disorder is at the origin of the observed domain wall creep. To investigate the effects of changing the disorder in the films, defects were introduced during crystal growth (a-axis inclusions) or by heavy ion irradiation, producing films with planar or columnar defects, respectively. The presence of these defects was found to significantly decrease the creep exponent μ, from 0.62-0.69 to 0.38-0.5 in the irradiated films and 0.19-0.31 in the films containing a-axis inclusions.
机译:原子力显微镜用于研究外延Pb(Zr_(0.2)Ti_(0.8))O_3薄膜中的铁电转换和纳米级域动力学。域大小的写入时间依赖性的测量揭示了一个两步过程,其中成核后是径向域生长。在这种生长过程中,畴壁速度表现出对电场的υ∝ exp-(1 / E)〜μ依赖性,这是蠕变过程的特征。在周期性电势下的随机成核和无序电势下的弹性歧管的规范蠕变运动中都对畴壁运动进行了分析。膜的尺寸暗示无序是观察到的畴壁蠕变的起源。为了研究改变膜中无序的影响,在晶体生长过程中(a轴夹杂物)或通过重离子辐照引入了缺陷,分别生产了具有平面或柱状缺陷的膜。发现这些缺陷的存在显着降低了蠕变指数μ,在辐照膜中蠕变指数从0.62-0.69降低到0.38-0.5,在包含a轴夹杂物的膜中蠕变指数从0.19-0.31降低。

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